Starch and its derivatives
have recently emerged as a sustainable
and renewable alternative for petroleum-based expanded polystyrene
(EPS) and expanded polypropylene (EPP) foam materials. In this study,
biodegradable foam materials were prepared from cassava starch using
a novel dual modification technique, combining microwave treatment
and freeze-drying. The foam materials were prepared from starch solutions
microwaved over different intervals. The starch-based foam materials
were characterized using Fourier transform infrared (FTIR) spectroscopy,
thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning
electron microscopy (SEM),
13
C nuclear magnetic resonance
(
13
C-NMR) spectroscopy, and compression set test. Moreover,
the water absorption capacities and density values of the foam materials
were measured according to ASTM standards. The biodegradability test
was carried out according to the aerobic compost environment test.
The lowest water absorption capacities of 65.56% and 70.83% were exhibited
for the cassava starch foam sample (MWB) prepared at a 20 s microwave
treatment time and immersed in distilled water for 2 and 24 h, respectively.
Furthermore, the lightweight cassava starch-based foam materials displayed
density ranging from 124 to 245 kg/m
3
. The biodegradation
test exhibited significant biodegradation of over 50% after 15 days
for all the foam materials prepared. These results suggest that the
dual-modified cassava starch-based biodegradable foams show potential
in sustainable packaging applications by replacing petroleum-based
materials.