Status and future plans for the BNL polarized H− source

Sluyters, T.; Alessi, J.; Kponou, A.

doi:10.1063/1.34401

Cited by 1 publication

(3 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…This capillary was further extruded to form an enlongated tip to minimize the shading of the tip (8). The bulb at the base of the extruded portion was very small to minimize gas retention (9). The extruded capillary was cut at a right angle to form a smooth edge.…”

Section: Methodsmentioning

confidence: 99%

“…The values of qM are obtained by integration of the differential doublelayer capacity curves according to Eq. [9]. The obtained values of qM and the corresponding values of b~, calculated according to Eq.…”

Section: Differential Double-layer Capacity Curves In Nonaque-mentioning

confidence: 99%

“…The aim of the present work was to investigate the kinetics of deposition-dissolution of transition metals in molten LiC1-KC1 eutectic. This solvent has been a popular one among previous investigators, and much thermodynamic data and some electrode kinetic data are available (9). Three metals were investigated in this work: iron,…”

Section: Differential Double-layer Capacity Curves In Nonaque-mentioning

confidence: 99%

See 2 more Smart Citations

Electrode Kinetics in Nonaqueous Aprotic Solvents

Jorné

Pai

1985

J. Electrochem. Soc.

View full text Add to dashboard Cite

The electrode kinetics of Na+ reduction are studied at dropping mercury electrode in four polar aprotic solvents, propylene carbonate (PC), dimethylformamide (DMF), dimethylsulfoxide (DMSO), and acetonitrile (AN), using the faradaic impedance method. The true rate constants measured for 1M NaClO4 in PC, DMF, DMSO, and AN are 0.38, 0.21, 0.05, and 0.35 cm‐s−1, respectively. The corresponding cathodic transfer coefficients are measured to be 0.62, 0.81, 0.43, and 0.42, respectively. Na+ reduction is found to be a simple charge‐transfer reaction, based on its conformance to the analysis using the classical Randles circuit. Using relative rate constants false(knormalshnormalt)normalrel , for Na+ with water as reference solvent, a standard potential scale for Na+/Na vs. NHE is developed for all four solvents and compared with standard potential scales for K+/K vs. NHE. The surface potentials of all four solvents are calculated to be positive and discussed in terms of solvent dipole orientation. Comparison of rate constants and free energy of Na+ solvation is made to determine the effect of solvation on the kinetics of Na+ reduction in PC, DME, DMSO, and AN. The trend of standard rate constants follows the trend of sodium ion solvation in the nonaqueous solvents PC≅AN

show abstract

Section: Methodsmentioning

confidence: 99%

Section: Differential Double-layer Capacity Curves In Nonaque-mentioning

confidence: 99%

Section: Differential Double-layer Capacity Curves In Nonaque-mentioning

confidence: 99%

See 1 more Smart Citation