The utilization of laser directed energy deposition (DED) for fabricating alloys offers the potential to customize their mechanical and physical properties, which cannot be achieved with traditional casting processes. In this work, DED adopted flat top laser was applied in the production of W6Mo5Cr4V2 alloy, a material widely used in industries such as mold‐making, double screw production, and crushing roller manufacturing. To minimize residual stress and potential defects, and enhance the performance of the deposited sample, it underwent a tempering heat treatment at 560°C for one hour. The deposited W6Mo5Cr4V2 alloy was found to be predominantly composed of martensite, carbide, and a minor amount of retained austenite, according to the analysis results. Upon tempering heat treatment, the retained austenite underwent a significant transformation into martensite, with secondary carbides precipitating and effectively reinforcing the mechanical properties of the W6Mo5Cr4V2 alloy. Furthermore, the microhardness value of the alloy was found to increase by 12% after tempering heat treatment. Both adhesive and abrasive wear were observed during the friction and wear process, resulting in a 10% reduction in friction coefficient, thereby significantly improving the wear resistance of the W6Mo5Cr4V2 alloy. The average tensile strength of the heat‐treated W6Mo5Cr4V2 sample was 762.34 MPa, which is higher than the average tensile strength of the deposited sample measured at 646.6 MPa. Notably, the tensile fracture displayed typical brittle characteristics.This article is protected by copyright. All rights reserved.