The Daniel K. Inouye Solar Telescope (DKIST) is designed to deliver accurate spectro-polarimetric calibrations across a wide wavelength range and large field of view for solar disk, limb and coronal observations. DKIST instruments deliver spectral resolving powers up to 300,000 in multiple cameras of multiple instruments sampling nanometer scale bandpasses. We require detailed knowledge of optical coatings on all optics to ensure we can predict and calibrate the polarization behavior of the system. Optical coatings can be metals protected by many dielectric layers or several-micron thick dichroics. Strong spectral gradients up to 60 • retardance per nanometer wavelength and several percent diattenuation per nanometer wavelength are observed in such coatings. Often, optical coatings are not specified with spectral gradient targets for polarimetry in combination to both average and spectral threshold type specifications. DKIST has a suite of interchangeable dichroic beam splitters using up to 96 layers. We apply the Berreman formalism in open-source Python scripts to derive coating polarization behavior. We present high spectral resolution examples on dichroics where transmission can drop 10% with associated polarization changes over a 1 nm spectral bandpass in both mirrors and dichroics. We worked with a vendor to design dichroic coatings with relatively benign polarization properties that pass spectral gradient requirements and polarization requirements in addition to reflectivity. We now have the ability to fit multi-layer coating designs which allow us to predict system level polarization properties of mirrors, anti-reflection coatings and dichroics at arbitrary incidence angles, high spectral resolving power and on curved surfaces through optical modeling software packages. Performance predictions for polarization at large astronomical telescopes requires significant metrology efforts on individual optical components combined with systems-level modeling efforts. We show our custom-built laboratory spectropolarimeter and metrology efforts on protected metal mirrors, antireflection coatings and dichroic mirror samples.