This study investigated
indicatory metals in the filterable (FPM2.5) and condensable
(CPM) particulate matter emitted from
six different types of stationary stacks (based on fuels and raw materials, n = 33), namely, coal boiler (COL), heavy oil boiler (HOL),
wood boiler (WOD), diesel boiler (DSL), natural gas boiler (NGS),
and incinerator (INR). FPM2.5 and CPM samples were collected
following U.S. EPA Method 201A and Method 202, respectively. The samples
were analyzed for mass concentrations and metal compositions. Results
showed that the concentration of CPM was higher than that of the FPM2.5 for all types of stacks except WOD. Comparability analysis
of FPM2.5, CPM, and TPM2.5 (FPM2.5 + CPM) metal profiles assessed by using the coefficient of divergence
(COD) showed a heterogeneous (COD = 0.32–0.99) relationship
among six groups of emission stacks. However, FPM2.5, CPM,
and TPM2.5 metal profiles within a group of stack revealed
homogeneous (COD = 0.19) to heterogeneous (COD = 0.79) relations.
Indicatory metals for COL were found to be Ca, Ba, V (FPM2.5), Se, Cd, and Co (CPM) and V, Se, and Co (TPM2.5). Similarly,
indicatory metals for HOL included Ca, V, Ni (FPM2.5),
V, Se, and Cd (CPM) and V, Co, and As (TPM2.5). Ca, Ni,
Ba (FPM2.5), Se, V, and Cd (CPM) and V, Cd, and As (TPM2.5) were recognized as indicatory metals for WOD boilers.
Similarly, K and Ca were found to be indicatory metals for DSL, NGS,
and INR. The indicatory metals for different emission sources and
for different particle fractions (FPM2.5 and CPM) reflect
the differences in fuel types, combustion temperatures, and particle
formation mechanisms. The results of the present study are expected
to provide valuable information for source apportionment modeling
and to better assess the contributions of the aforementioned emission
sources to the ambient concentrations of PM2.5 and metal
elements.