Based on the proposed criterion of the type of heating, a classification of the sources of pulsed electron beams was carried out, both to obtain a better understanding of the nature of the thermal processes occurring under irradiation and to predict their suitability for certain applications. The melting thresholds of materials were calculated over a wide ranges of accelerating voltages and pulse durations. On the basis of calculations, a refractoriness series was proposed for metals for surface–volume pulsed heating.