1996
DOI: 10.1021/ja961007c
|View full text |Cite
|
Sign up to set email alerts
|

Stereochemical Control in Metalloporphyrin Chemistry:  Synthesis and Characterization of cis- and trans-Sn(porphyrin)Ph2

Abstract: In metalloporphyrin chemistry, cis versus trans coordination geometries are generally assumed to be controlled by the nature of the metal ion, with the trans (or axial) arrangement being

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

1
26
0

Year Published

1996
1996
2024
2024

Publication Types

Select...
6
2
1

Relationship

0
9

Authors

Journals

citations
Cited by 29 publications
(28 citation statements)
references
References 15 publications
1
26
0
Order By: Relevance
“…A large number of tin(IV) porphyrins of the type [(P)SnX 2 ] (P is either tetraaryl or octaethyl porphyrin and X is an 'inorganic' axial ligand such as halide, OH -, ClO 4 -, S 2or Se 2-) [7-10, 15-21, 36-39] and organometallic complexes of the type [(P)Sn(R) 2 ] (R = alkyl/aryl group) [40,41] are well known in the literature. Relatively less well studied are the corresponding porphyrins of the type [(P)Sn(OR) 2 ] where OR is an organic (alkoxy/aryloxy/acidoxo etc.)…”
Section: Resultsmentioning
confidence: 99%
“…A large number of tin(IV) porphyrins of the type [(P)SnX 2 ] (P is either tetraaryl or octaethyl porphyrin and X is an 'inorganic' axial ligand such as halide, OH -, ClO 4 -, S 2or Se 2-) [7-10, 15-21, 36-39] and organometallic complexes of the type [(P)Sn(R) 2 ] (R = alkyl/aryl group) [40,41] are well known in the literature. Relatively less well studied are the corresponding porphyrins of the type [(P)Sn(OR) 2 ] where OR is an organic (alkoxy/aryloxy/acidoxo etc.)…”
Section: Resultsmentioning
confidence: 99%
“…There are six derivatives [366,466,571,626,634] where a square plane is created by a tetradentate macrocycle with the axial positions occupied by monodentate C-donor ligands. The structures of two of them are shown in Figures 8 and 9.…”
Section: ιοmentioning
confidence: 99%
“…[18][19][20][21] Organometallic chemistry of these metal macroheterocycles has been developed mainly for metalloporphyrins due to their solubility in organic solvents that allows one to obtain crystals of indium, gallium and tin porphyrins with alkyl, vinyl, phenyl or phenylacetylenyl substituents at the metal centers. [8][9][10][11][14][15][16][17] Compounds with tin porphyrin (SnP) can contain one and two alkyl or phenyl ligands at the metal center, and can be obtained by oxidative addition of CH 3 I to Sn II P, 10 direct synthesis from Li 2 P and SnCl 2 R 2 , or the interaction of the R 2 Mg and Grignard reagents with Sn IV Cl 2 P. 11 At the same time, only a few such compounds are known for metal phthalocyanines. For example, the structure of phenylindium octakis(hexyl)phthalocyanine can be found in the CCDC database only for metal phthalocyanines with phenyl substituents at the metal atoms.…”
Section: Introductionmentioning
confidence: 99%