Stereoelectronic control of Cope rearrangement energetics through remote double bonds in novel, rigid polycyclic frames

Mehta, Goverdhan; Reddy, S. Hari Krishna; Pattabhi, Vasantha; Bhanumathi, S.; Pramanik, Animesh; Chandrasekhar, Jayaraman

doi:10.1039/p19930001539

J. Chem. Soc., Perkin Trans. 1

1993

DOI: 10.1039/p19930001539

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Stereoelectronic control of Cope rearrangement energetics through remote double bonds in novel, rigid polycyclic frames

Goverdhan Mehta¹,

S. Hari Krishna Reddy²,

Vasantha Pattabhi³

et al.

Abstract: The presence and orientation of remote double bonds are shown to completely alter the shapes of Cope rearrangement energy profiles in a heptacyclic system.11 G. M. Sheldrick (1976), SHELX 76. Program for crystal structure determinations,

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Stereoelectronic control of Cope rearrangement energetics through remote double bonds in novel, rigid polycyclic frames

Abstract: The presence and orientation of remote double bonds are shown to completely alter the shapes of Cope rearrangement energy profiles in a heptacyclic system.11 G. M. Sheldrick (1976), SHELX 76. Program for crystal structure determinations,

Cited by 0 publications

References 6 publications

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