2024
DOI: 10.1002/cjoc.202400502
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Stereoselective Gridization of Ladder‐Type Grids with Four Chiral Centers

Yang Li,
Yueting Pu,
Zheng Zhang
et al.

Abstract: Comprehensive SummaryTo address the stereoselective synthesis challenge in π‐stacked grids with four chiral centers, we utilized coplanar and highly rigid 11,12‐dihydroindeno[2,1‐a]fluorene‐11,12‐diol and 2,2'‐bithiophene as synthons, employing Friedel‐Crafts gridization (FCG). Leveraging the supramolecular interactions of S···S and π···π within the thiophene moiety, along with the steric effect of the 11,12‐dihydroindeno[2,1‐a]fluorene scaffold, we successfully achieved the exclusive generation of a single is… Show more

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