Stereoselective synthesis of 1,6-diazecanes by a tandem aza-Prins type dimerization and cyclization process

Abstract

We report the stereocontrolled synthesis of 1,6-diazecanes via tandem aza-Prins type reaction of N-acyliminium ion with allylsilane. It involves aza-Prins type dimerization and cyclization in a single-step operation. This reaction...