2018
DOI: 10.1002/ejoc.201801623
|View full text |Cite
|
Sign up to set email alerts
|

Stereoselective Synthesis of the β‐Amino Acid Moiety of Fijiolide A

Abstract: An enantioselective synthesis of the β‐amino acid moiety of fijiolide A is described. Starting from eugenol, two sulfamates could be obtained on gram scale as substrates for an enantioselective C–H amination using Rh2(R/S‐nap)4. Acylation and ring opening of the resulting oxathiazinanes, followed by stepwise oxidation of the corresponding amino alcohol and TES‐protection of the catechol gave rise to Cramer's amino acid fragment from the total synthesis of fijiolide A.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

2019
2019
2024
2024

Publication Types

Select...
2

Relationship

0
2

Authors

Journals

citations
Cited by 2 publications
references
References 14 publications
(28 reference statements)
0
0
0
Order By: Relevance