Stereospecific Synthesis of (4E,10Z)- 4,10-Tetradecadienyl Acetate, the Major Sex Pheromone of Apple Leaf Miner Moth, Phyllonorycter ringoniella

Awalekar, Ramchandra; Jagadhane, Kishor S.; Usmani, Shams; Salunkhe, Shilpa; Jamale, Dattatray; Hangirgekar, Shankar; Kolekar, Govind B.; Anbhule, Prashant V.

doi:10.2174/1570178617999200922145900

Cited by 3 publications

(5 citation statements)

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“…Finally, the charge transport model fitting results are shown in Figures S4 and S5. The results suggested that the TC devices follow the Ohmic and Child's square law conduction at low and high voltage regions (HRS) and Ohmic conduction was found to be dominant during LRS [35,36] …”

Section: Resultsmentioning

confidence: 99%

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Tetraphenylethene Carbothioamide‐Based Organic Stimuli‐Responsive Mechanochromic Memristive Devices with Non‐Volatile Memory and Synaptic Learning Functionalities

et al. 2023

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A tetraphenylethene‐based organic material (TC) was synthesized to demonstrate mechanochromic memristive properties. The synthesized material shows aggregation‐induced emission and mechanochromic properties. The solvent optimization study reveals that the ethyl acetate‐based TC switching layer shows good resistive switching (RS) properties. To get the mechanochromic memristive properties, different external stresses (ground, heat, and fume) were applied to the TC materials, and these materials were used for the fabrication of switching layers. The results asserted that ethyl acetate and grinding‐based TC devices show good digital‐type RS effects and non‐volatile memory properties. On the other hand, heating and fuming‐based TC devices show analog and quasi‐digital type RS effects, respectively, and mimic various biological synaptic properties such as potentiation‐depression, excitatory postsynaptic current, and paired‐pulse facilitation index. The present investigation is important to fabricate stimuli‐responsive memory and artificial synaptic devices for futuristic non‐volatile memory and neuromorphic computing applications.

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Section: Resultsmentioning

confidence: 99%

“…The results suggested that the TC devices follow the Ohmic and Child's square law conduction at ChemistrySelect low and high voltage regions (HRS) and Ohmic conduction was found to be dominant during LRS. [35,36]…”

Section: Chemistryselectmentioning

confidence: 99%

Tetraphenylethene Carbothioamide‐Based Organic Stimuli‐Responsive Mechanochromic Memristive Devices with Non‐Volatile Memory and Synaptic Learning Functionalities

et al. 2023

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“…The precipitate was filtered after the addition of 25 mL of water (ice-cold). The reaction progress was checked using TLC, and the final pale-yellow residue was purified by column chromatography with pet ether/ethyl acetate (v/v = 90/10) to get ( E )-ethyl 2-cyano-3-(4′-(diphenyl amino)-[1,1′-biphenyl]-4-yl) acrylate (142.0 mg, 85% yield). , …”

Section: Methodsmentioning

confidence: 99%

A Reversible Mechanochromic AIEgen Based on Triphenylamine for the Selective Detection of Vitamin B2 (Riboflavin) in Aqueous Media and Histotoxicity

Jagadhane,

Birajdar,

Kolekar

et al. 2024

Chem. Res. Toxicol.

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Metrics & MoreArticle Recommendations * sı Supporting Information ABSTRACT:) is a novel luminogen based on triphenylamine. It has been fully synthesized and characterized, exhibiting an incredible photophysical phenomenon known as aggregationinduced emission (AIE). This work describes a fluorescent sensor that detects vitamin B2 in mixed aqueous media with high selectivity and a low limit of detection as well as a mechanism for reversible mechanochromic luminescence. Moreover, the molecule was validated for its nontoxicity in water using a histotoxicological study. Fish subjected to two different concentrations of the "novel luminogen" that displayed photophysical phenomena during sensing of vitamin B2 (riboflavin) in mixed aqueous media did not exhibit any significant differences in the structural makeup of their liver, kidney, gills, brain, and muscle tissues when compared with the control group.

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“…Furthermore, we employed TPE-SKJ material as an emissive layer for an organic light-emitting diode (OLED). The device shows a maximum 1.62% external quantum efficiency, higher than nondoped emitting layer-based green OLEDs. , …”

Section: Introductionmentioning

confidence: 91%

“…The device shows a maximum 1.62% external quantum efficiency, higher than nondoped emitting layerbased green OLEDs. 26,30…”

Section: Introductionmentioning

confidence: 99%

Multifunctional Fluorescent Tetraphenylethene-Based Reversible Mechanochromism for Highly Selective Detection of MnO₄^– in Aqueous Media and Green Organic Light Emitting Diode Applications

Jagadhane

Butcher

Dongale

et al. 2023

Crystal Growth & Design

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Ethyl 2-cyano-3-(4-(1,2,2-triphenylvinyl) phenyl) acrylate (TPE-SKJ), a newly synthesized luminogen based on tetraphenylethene, with single crystal analysis exhibits photophysical phenomena such as aggregation-induced emission (AIE); reversible mechanochromic, solvatochromic, organic light emitting diode; and chemical sensing in aqueous media with great selectivity and a low limit of detection. The synthesized material demonstrates high selectivity and sensitivity capacity for sensing MnO4 – in mixed aqueous media (water/acetonitrile, v/v, 9/1). The detection limit for MnO4 – was found to be 0.086009 μg mL–1 with a quantum yield (Φ) of 11%. Moreover, we employed TPE-SKJ material in an organic light-emitting diode (OLED) as an emissive layer. The device shows a maximum of 1.62% external quantum efficiency, higher than nondoped emitting layer-based green OLEDs. The present results will encourage ongoing research into the design of novel stimuli-responsive organic materials with switchable properties based on their supramolecular interactions for numerous applications.

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Stereospecific Synthesis of (4E,10Z)- 4,10-Tetradecadienyl Acetate, the Major Sex Pheromone of Apple Leaf Miner Moth, Phyllonorycter ringoniella

Cited by 3 publications

References 0 publications

Tetraphenylethene Carbothioamide‐Based Organic Stimuli‐Responsive Mechanochromic Memristive Devices with Non‐Volatile Memory and Synaptic Learning Functionalities

Tetraphenylethene Carbothioamide‐Based Organic Stimuli‐Responsive Mechanochromic Memristive Devices with Non‐Volatile Memory and Synaptic Learning Functionalities

A Reversible Mechanochromic AIEgen Based on Triphenylamine for the Selective Detection of Vitamin B2 (Riboflavin) in Aqueous Media and Histotoxicity

Multifunctional Fluorescent Tetraphenylethene-Based Reversible Mechanochromism for Highly Selective Detection of MnO₄^– in Aqueous Media and Green Organic Light Emitting Diode Applications

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Stereospecific Synthesis of (4E,10Z)- 4,10-Tetradecadienyl Acetate, the Major Sex Pheromone of Apple Leaf Miner Moth, Phyllonorycter ringoniella

Cited by 3 publications

References 0 publications

Tetraphenylethene Carbothioamide‐Based Organic Stimuli‐Responsive Mechanochromic Memristive Devices with Non‐Volatile Memory and Synaptic Learning Functionalities

Tetraphenylethene Carbothioamide‐Based Organic Stimuli‐Responsive Mechanochromic Memristive Devices with Non‐Volatile Memory and Synaptic Learning Functionalities

A Reversible Mechanochromic AIEgen Based on Triphenylamine for the Selective Detection of Vitamin B2 (Riboflavin) in Aqueous Media and Histotoxicity

Multifunctional Fluorescent Tetraphenylethene-Based Reversible Mechanochromism for Highly Selective Detection of MnO4– in Aqueous Media and Green Organic Light Emitting Diode Applications

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Multifunctional Fluorescent Tetraphenylethene-Based Reversible Mechanochromism for Highly Selective Detection of MnO₄^– in Aqueous Media and Green Organic Light Emitting Diode Applications