1989
DOI: 10.1021/ja00202a025
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Steric and electronic factors that control two-electron processes between metal carbonyl cations and anions

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Cited by 30 publications
(7 citation statements)
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“…On the reverse scan, two anodic peaks are seen at À0.64 and À0.27 V, corresponding to the oxidation of products formed by the chemical reaction which follows the forward electron transfer. By comparison with authentic samples and with literature values [13], these anodic peaks were assigned to [Co(CO) 3 and [Co(CO) 4 ] À , respectively. Comparison of the peak current for the reduction of compound 1 with that of the oneelectron reduction of tris(dibenzoylmethanato)iron and the two-electron reduction of [CpFe(CO) 2 ] 2 at the same concentration indicates that the reduction of compound 1 is a one-electron process.…”
Section: Resultsmentioning
confidence: 83%
“…On the reverse scan, two anodic peaks are seen at À0.64 and À0.27 V, corresponding to the oxidation of products formed by the chemical reaction which follows the forward electron transfer. By comparison with authentic samples and with literature values [13], these anodic peaks were assigned to [Co(CO) 3 and [Co(CO) 4 ] À , respectively. Comparison of the peak current for the reduction of compound 1 with that of the oneelectron reduction of tris(dibenzoylmethanato)iron and the two-electron reduction of [CpFe(CO) 2 ] 2 at the same concentration indicates that the reduction of compound 1 is a one-electron process.…”
Section: Resultsmentioning
confidence: 83%
“…[PPN] + [Mn(CO)4(PPh3)] -. The complex was synthesized according to a literature method 7 with slight modification. To a solution of Mn2(CO)8(PPh3)2 12 (0.33 g, 0.38 mmol) in 10 mL of THF at 0 °C was added Li(C2H5)3BH (1.0 M THF solution, 0.96 mL, 0.96 mmol).…”
Section: Methodsmentioning
confidence: 99%
“…PPN Fp À was prepared beforehand and FpLi was obtained in situ by the exchange reactions of FpK with PPN Cl À [39] and LiCl accordingly. If necessary THF was replaced with another solvent.…”
Section: Methodsmentioning
confidence: 99%