In the construction sector, enhancing the thermomechanical attributes of building materials is of significant importance. This research is centered on examining kaolin-enhanced rammed earth bricks, which are augmented through an alkaline solution to facilitate geopolymerization, creating a synergy between geopolymer and soil. Physico-chemical analysis methods such as X-ray diffraction (XRD), scanning electron microscopy (SEM-EDX), Fourier transform infrared spectroscopy (FTIR), differential thermal and gravimetric analysis (DTA-GTA) and particle size analysis were used to characterize the properties and reactive potential of studied materials. The chemical composition analysis revealed that the soil and kaolin contained substantial amounts of Calcite (32.2%), Quartz (26.5%), Muscovite (15.44%), Nimesite (18%), and in kaolin, Quartz (68.3%) and Illite (30.1%) were predominant. Samples with different kaolin-geopolymer ratios (0%, 3%, 4%, 5% and 6%) were designed and prepared for both mechanical (compressive and tensile strength) and thermal testing. The results obtained indicate a significant improvement in the structural integrity of earth bricks with increasing kaolin-geopolymer content when combined with an alkaline solution. However, this improvement is accompanied by a reduction in thermal resistance after 28 days.