2024
DOI: 10.1039/d3cs00952a
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Stimuli-responsive synthetic helical polymers

María Lago-Silva,
Manuel Fernández-Míguez,
Rafael Rodríguez
et al.

Abstract: Synthetic dynamic helical polymers (supramolecular and covalent) and foldamers share the helix as a structural motif.

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Cited by 40 publications
(12 citation statements)
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References 475 publications
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“…. 1 H NMR spectra were recorded on a Bruker AV 500 spectrometer ( 1 H: 500 MHz, 13 C: 125 MHz). ESI-MS analyses were performed on a Thermo Scientific Q Exactive HF Orbitrap-FTMS.…”
Section: Instruments and Measurementsmentioning
confidence: 99%
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“…. 1 H NMR spectra were recorded on a Bruker AV 500 spectrometer ( 1 H: 500 MHz, 13 C: 125 MHz). ESI-MS analyses were performed on a Thermo Scientific Q Exactive HF Orbitrap-FTMS.…”
Section: Instruments and Measurementsmentioning
confidence: 99%
“…The mixture was allowed to increase to room temperature with stirring for 12 h. After evaporation of solvents with vacuum, column chromatography (0% ∼ 50% DCM/HEX gradient) followed by recrystallization from HEX afforded the product as lightyellow crystals (199.65 mg, 47%). 1…”
Section: Instruments and Measurementsmentioning
confidence: 99%
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“…Artificially synthesized chiral polymers, as a result, have garnered extensive attention from chemists. 9–16…”
mentioning
confidence: 99%
“…Chiroptical nanomaterials with circularly polarized luminescence (CPL) performance are drawing substantial interest in multidisciplinary fields due to their promising potential in 3D displays, optical sensors, bioimaging, asymmetric catalysis, etc. Among various CPL-active architectures, CPL nanofibers have been widely studied, and most of them are prepared by a self-assembly strategy. However, the nanofibers prepared by self-assembly are largely limited to specific systems, and the resulting products are discontinuous, which may not be conducive to practice applications. Delightedly, the past few years have witnessed the rapid development of an electrospinning technique, and it has proved to be an effective method for constructing flexible and continuous CPL nanofibers with a controlled morphology, uniformity, and the desired optical properties. The advantages of electrospinning include ease of operation, reliable reproducibility, and low cost.…”
mentioning
confidence: 99%