By combining artificial intelligence (AI) algorithms with blockchain technology, the AI-powered decentralized Recruitment System on the Blockchain (ADRSoB) offers a cutting-edge method for completely changing the hiring process. This study aims to assess the effectiveness and impact of ADRSoB in several areas, such as user satisfaction, bias mitigation, candidate selection quality, efficiency, and transparency. From a methodological standpoint, case studies, research papers, and current literature pertinent to ADRSoB were compiled using a secondary data-based review article approach. Principal results show that ADRSoB increases user happiness while promoting transparency, mitigating biases, improving applicant selection quality, and streamlining recruiting processes. However, policy implications such as encouraging technology use, guaranteeing data privacy legislation, and fostering fairness in algorithmic systems are required due to obstacles to technology adoption, data privacy issues, and bias in algorithmic decision-making. ADRSoB has enormous potential to change hiring procedures while addressing critical issues and encouraging moral and responsible hiring in the digital era.