5Potatoes are an important staple crop, grown in many parts of the world. Although ozone 6 deposition to many vegetation types has been measured in the field, no data have been 7 reported for potatoes. Such measurements, including the latent heat flux, were made 8 over a fully-grown potato field in central Scotland during the summer of 2006, covering a 9 4-week period just after rainfall and then dry, sunny weather. The magnitude of the flux 10 was typical of many canopies showing the expected diurnal cycles. Although the bulk-11 canopy stomatal conductance declined as the field dried out (~300 mmol-O 3 m -2 s -1 to 12 ~70 mmol-O 3 m -2 s -1 ), the total ozone flux did not follow the same trend, indicating that 13 non-stomatal deposition was significant. Over a dry surface non-stomatal resistance (R ns ) 14 was 270-450 s m -1 , while over a wet surface R ns was ~50% smaller and both decreased 15 with increasing surface temperature and friction velocity. From the variation with relative 16 humidity (RH) it is suggested that three processes occur on leaf surfaces: on a very dry 17 surface ozone is removed by thermal decomposition, possibly enhanced by photolytic 18 reactions in the daytime and so R ns decreases as temperature increases; at 50-70% RH a 19 thin film of liquid blocks the "dry" process and resistance increases; above 60-70% RH 20 sufficient surface water is present for aqueous reactions to remove ozone and resistance 21 decreases. 22Keywords: eddy-correlation; surface conductance; ozone critical levels; AOT40, AFst6; 23 stomatal uptake; non-stomatal; dry deposition 24 Capsule: Ozone deposition to a potato crop depends not only on stomatal uptake but is 25 enhanced by increasing surface temperature or the presence of water. 26