Particle rafts are a new kind of
soft matter formed by self-organization
on the interface, which possesses mechanical properties between fluid
and solid, and they have been widely used in many industrial fields.
In the present study, the compression experiment of a circular particle
raft is first performed, where an SDS (sodium dodecyl sulfate)-coated
metal ring is placed around its periphery. When the surfactant diffuses,
the particle raft shrinks, and its shrinkage ratio increases with
the increase in the surfactant concentration, where the experimental
results are consistent with the numerical simulation. Next, the relationship
between the initial surface tension difference of SDS and the radius
shrinkage of the particle raft is obtained by dimensional analysis.
In what follows, the diffusion model is built to quantify the diffusion
process of SDS at the liquid–gas interface, and then the analytical
concentration solution of the concentration of SDS at the periphery
of particle raft is given. The particle raft is viewed as an elastic
circular plate under the action of the radial pressure, which originates
from the surface tension difference, which has been verified by the
experimental result. These explorations cast a new light on how to
apply loads to measure mechanical properties of soft matter, which
also provide some inspirations on the design of microsensors and microfluidics.