Alkali-activated slag (AAS) mortars were prepared using pottery sand as a fine aggregate in a ratio of 1 : 1.75 using a blend of sodium silicate and NaOH as an alkaline activator at room temperature. e effects of sodium oxide content and silicate moduli on the setting time, fluidity, consistency, compressive strength, and drying shrinkage of different AAS mortars were determined. ese results revealed that sodium oxide content and silicate modulus had little effect on the setting time and workability of the mortar; however, they did have a significant effect on their mechanical performance and drying shrinkage levels. All the AAS mortars exhibited faster setting times, better workability, and higher early and late compressive strength compared to traditional mortars. Optimum compressive strength was achieved at 93 and 123 MPa after 1 d and 28 d, respectively, using a silicate modulus of 1.2 and Na 2 O content of 8%. e microstructures of mortars were characterized using scanning electron microscopy with energy dispersive spectrometric (SEM/EDS) and mercury intrusion porosimetry (MIP). ese results reveal that AAS mortars containing pottery sand as a fine aggregate may represent a promising building material with improved properties for use in the construction industry.