a b s t r a c tA newly developed Mg-Sn-Zn-Al based alloy shows substantial strengthening by artificial aging. A Na-doped Mg-5.4Sn-4.2Zn-2.0Al-0.2Mn-0.1Na (TZAM5420À0.1Na) (wt.%) alloy exhibited a significant increase in yield strength from 243 to 347 MPa by a T6 treatment due to the uniform dispersion of nanoscale precipitates by aging. The trace addition of Na causes the formation of Sn-Na co-clusters in the early stage of aging, which provides heterogeneous nucleation sites for Mg 2 Sn precipitates. However, Na strongly segregates at grain boundaries and this degrades the ductility significantly. To overcome this problem, we developed a Na-free Mg-6.6Sn-5.9Zn-2.0Al-0.2Mn (TZAM6620) alloy, in which nano-scale MgZn 2 precipitates are uniformly dispersed by double aging. Pre-aging caused the formation of Zn-rich Guinier Preston zones, which acted as heterogeneous nucleation sites for the MgZn 2 precipitates. The double-aged TZAM6620 alloy exhibited a very high yield strength of 370 MPa with large elongation of 14%.