Geopolymer concrete, an environmentally friendly alternative to typical Portland cement-based concrete, has been gaining popularity due to its less carbon footprint and increased durability. This study investigates the molarity impact of sodium hydroxide (NaOH) on the characteristics of geopolymer concrete, with the inclusion of Nano Silica as a pozzolanic material. The mechanical and flexural properties of Geopolymer concrete (GPC) incorporating Nano Silica at NaOH (sodium hydroxide) molarities of 2M, 4M, 6M, 8M and 10M under ambient curing are evaluated. Flyash, GGBS-ground granulated blast furnace slag, and Silicon Dioxide (Nano Silica) are utilized as binders in the specially blended Geopolymer concrete mix, which is activated by an alkaline solution. The inclusion of Nano-Silica at about 3% of the weight of the binder ingredient is kept constant during our investigation. Nano Silica mostly works as a filler ingredient in concrete. The mechanical properties, fracture energy (GF), and stress intensity ratio or factor (KIC) of geopolymer concrete specimens of notched unreinforced beams (GPCUB) are among the metrics investigated. All of these findings of Geopolymer specimens are compared to those of Ordinary Portland Cement Concrete (PCC) specimens. The primary objective is to determine the impact of different NaOH molarities and Nano Silica inclusion on the ability of geopolymer-based concrete to withstand cracking and modify its behaviour. As the concentration of NaOH in GPC samples increases, so their mechanical characteristics increases. Silica dissolution has the greatest impact in samples treated with a 10M NaOH solution when compared to other molarities and PCC. This implies that incorporating Nano Silica at varied molarities can effectively improve Geopolymer behaviour by increasing its ability to tolerate brittle failure and fracture propagation. The findings of this study have the potential to give useful insights into the most suitable combination of sodium hydroxide molarity and Nano silica concentration for improved geopolymer concrete characteristics. Understanding these interactions becomes essential for the widespread use of geopolymer concrete for construction applications, which contributes to more sustainable and ecologically friendly practices.