superior properties of the substrate (e.g., strength, stiffness, and toughness). [2] This has allowed for applications in new fields, such as in engineering and medicine. [1,3] Such new applications include coatings of antifouling-antimicrobial hydrogels for infection prevention, [4] hydrogel adhesion to metal substrates for marine antifouling, [5] coatings of mechanically matched hydrogels to improve the biocompatibility of neural implants, [6] chemical-sensing hydrogel interferometerbased sensing platforms, [7] and glass fiber hydrogel coatings for selective oil-water separation. [8] Hydrogel coatings can be also applied to concrete materials. Concrete is widely used as a building material due to its low cost, high strength, good durability, plasticity, and versatility. [9][10][11] However, concrete structures are vulnerable to corrosion and weathering by the external environment (freezing, acid rain, etc.) due to their hydrophilicity and porous structure. [10] Many researchers have put substantial effort into fixing concrete damage. Xu et al. coated concrete with a colorful superhydrophobic material. [10] The coated concrete had enhanced anti-icing, anticorrosion, and self-cleaning properties. Song et al. coated concrete with microcapsules containing a healing agent to prevent the deterioration of the concrete. [12] In addition, because of the excellent properties of concrete, many concrete structures have been built in urban areas. This has caused environmental problems such as high energy consumption in city centers, global warming caused by refrigerants in cooling equipment, ozone layer depletion, urban heat island phenomenon, and poor indoor air quality. [13] Feng et al., [13] Cui et al., [14] and Rotzetter et al. [15] stated there may be an energy saving effect by cooling buildings using the evaporation heat of hydrogel. Since concrete structures and the external environment are interconnected, research to address the issues with concrete structures is urgently needed. In particular, in light of numerous studies, hydrogels are considered a promising material to solve the problem between the concrete and the environment.In our previous study, we developed a NC hydrogel that strongly adheres to concrete. [16] In general, for strong adhesion between the hydrogel and the substrate, surface modification of the substrate and the formation of a primer layer are essential. [17,18] On the other hand, nanosilicate-based hydrogels have excellent coating durability without pretreatment due to the following factors: (1) NC hydrogel adheres to concrete by chemical reaction between nanosilicate and portlandite. [19] Hydrogels can be coated on various substrates to add a variety of functions to the substrates. In this study, hydrogel is coated on concrete that widely used as a building material. In general, in order to coat hydrogel on concrete, a prior process such as surface modification or primer layer coating is essential. However, this process is time consuming and requires the use of toxic chemicals. In this study,...