2002
DOI: 10.1103/physrevlett.88.226104
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Stress Relief as the Driving Force for Self-Assembled Bi Nanolines

Abstract: Bi nanolines self-assemble on Si(001) and are remarkable for their straightness and length-they are often more than 400 nm long, and a kink in a nanoline has never been observed. Through electronic structure calculations, we have found an energetically favorable structure for these nanolines that agrees with our scanning tunneling microscopy and photoemission experiments; the structure has an extremely unusual subsurface structure, comprising a double core of seven-membered rings of silicon. Our proposed struc… Show more

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Cited by 108 publications
(94 citation statements)
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“…1(c)]. In this respect these nanowires are different from single dimer rows of Ge or Bi on Si(001) which are sometimes considered as nanowires [10]. However, those wires have no lateral Ge-Ge or Bi-Bi bonds, but only bonds to the underlying substrate.…”
mentioning
confidence: 99%
“…1(c)]. In this respect these nanowires are different from single dimer rows of Ge or Bi on Si(001) which are sometimes considered as nanowires [10]. However, those wires have no lateral Ge-Ge or Bi-Bi bonds, but only bonds to the underlying substrate.…”
mentioning
confidence: 99%
“…DFT has found it to have the lowest energy of any Bi/Si structure calculated, including a monolayer coverage of Bi, 15 but there has been no direct experimental confirmation of the reconstructed core. The pattern of dots seen by STM within the stripe is impossible to reconcile with unreconstructed diamond Si but matches closely that expected from termination of the dangling bonds in the Haiku structure by hydrogen.…”
mentioning
confidence: 99%
“…13 However, their width varies along their length, in odd multiples of the Si lattice parameter. Similarly, the Bi/Si͑001͒ nanolines 11,14,15 grow perfectly straight on flat terraces well clear of any step edges, and their length, limited only by the extent of the Si͑001͒ terraces and by surface defects, can also exceed 1 m. But Bi nanolines offer a decisive advantage compared to RENWs as follows: their width is invariant, exactly four Si dimers, or 1.54 nm, without kinks.…”
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confidence: 99%
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“…These reconstructions are not metallic, but one of the few examples of atomically perfect 1D systems on Si. [50][51][52][53] A good review on these structures is found in Ref. 54.…”
Section: Introductionmentioning
confidence: 99%