2012
DOI: 10.14723/tmrsj.37.303
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Stretchable and Highly Conductive Polymer Films

Abstract: Stretchable and highly conductive films made of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) (PEDOT/PSS) were prepared by casting the PEDOT/PSS aqueous dispersion as colloidal gel particles containing xylitol and subsequent heating. The electrical conductivity and elongation at break of the PEDOT/PSS film containing 50 wt% of xylitol significantly increased from 0.46 S/cm to 114 S/cm and from 4% to 33%, respectively, by heating at 140 °C in air for 1 h. It was found that the xylitol had… Show more

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Cited by 18 publications
(14 citation statements)
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“…Small molecular plasticizers, such as surfactants (Zonyl, 73 xylitol 74 Triton X-100 75 and so on ref. 76 and 77) and co-solvents could improve the processability or the work function in specific applications of PEDOT:PSS, and they may also significantly alter the mechanical properties.…”
Section: Molecular Level Miscible Polymer Blendsmentioning
confidence: 99%
“…Small molecular plasticizers, such as surfactants (Zonyl, 73 xylitol 74 Triton X-100 75 and so on ref. 76 and 77) and co-solvents could improve the processability or the work function in specific applications of PEDOT:PSS, and they may also significantly alter the mechanical properties.…”
Section: Molecular Level Miscible Polymer Blendsmentioning
confidence: 99%
“…The electrical conductivity is caused by the delocalized π-electrons within its chemical structure and the presence of sulfonated polystyrene (PSS). It was adopted due to its known electronic conduction, biocompatibility, high transparency (≥90%) and particularly for its mechanical flexibility (E ≃ 1.2 GPa) [16,17,18], making it suitable for either sensing or stimulating microstructures [31]. Moreover, previous studies suggest that this polymer can provide a gauge factor in the range of 0.4817.8 [19,20,21].…”
Section: Methodsmentioning
confidence: 99%
“…The strain gauges were modelled assuming a linear isotropic and elastic material. Values reported in the literature were used for the Youngs Modulus (90 GPa, 2 GPa) and Poisson ratio (0.31, 0.35) of titanium (Ti) and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), respectively [16,17,18,25].…”
Section: Strain Gauges On Pdms Membranesmentioning
confidence: 99%
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“…However, reliably enhancing its conductivity remains challenging despite the decade-long research effort. [16,22,31,37,[39][40][41][42][43][44][45][46][47] Most of the studies focused on the improvement of the conductivity while the stretchability was less investigated. [48][49][50][51] Our group has recently shown the benefits of a polyethylene oxide (PEO) network within PEDOT:PSS for microactuators with an excellent electromechanical response.…”
Section: Introductionmentioning
confidence: 99%