“…Therefore, over the past decade, chemical-based information encryption strategies are attracting increasing attention for meeting the challenge of information recording and encryption. − Among the relative encryption materials, fluorescent materials have aroused extensive attention due to the intelligence capability to sense, store, analyze, and respond to the external stimuli (solvents, ions, light, molecules, mechanical force, etc. ), making these materials have potential applications in sensors, bioimaging, displays, optical recording, and information security. − Meanwhile, fluorescence response endows the luminescent materials with intelligence, which can be displayed by an optical signal output accompanying with the obvious luminescence change such as quenching, enhancement, and emission peak shift toward the external stimuli. − Using the fluorescence response mechanism of fluorescent materials toward the external stimuli, chemical-based information security can realize the information storage, encryption, decryption, and anticounterfeiting benefiting from the superior selectivity and unique fluorescence response and therefore strengthen the information security level. In recent years, smart hydrogels, as one of the representative fluorescent materials, are also employed to improve the information security.…”