Series of glasses based on (75-x)TeO 2 -15MgO-10Na 2 O-xNd 2 O 3 , where x=0, 1.0, 2.0 and 3.0, are synthesized by conventional melt-quenching technique. The nanoglass particles are derived from heat treatment of this glass near crystallisation temperature for 3 hours. The existence of nanocrystalline nature of this glass is confirmed by x-ray diffraction (XRD) technique followed by calculation using Scherrer equation. Meanwhile, the crystallization temperature, Tc determined usingDifferential thermal analysis (DTA). The fluorescence spectra of Nd 3+ ions exhibit emission transition of 2 P 3/2 → 4 I 9/2 , 4 G 7/2 → 4 I 9/2 , 2 H 11/2 → 4 I 9/2 , and 4 F 9/2 → 4 I 9/2 under 765 nm excitation wavelengths.