Electron-initiated chemistry with chemically relevant
electron
energies (10–200 eV) is at the heart of several high-energy
processes and phenomena. To probe these dissociation and fragmentation
reactions with femtosecond resolution requires the use of femtosecond
lasers to induce ionization of the polyatomic molecules via electron
rescattering. Here, we combine noncommensurate fields with intensity-difference
spectra using methanol as a model system. Experimentally, we find
orders of magnitude enhancement in several product ions of methanol
when comparing coherent vs incoherent combinations of noncommensurate
fields. This approach not only mitigates multiphoton ionization and
multicycle effects during ionization but also enhances tunnel ionization
and electron rescattering energy.