2019
DOI: 10.13005/ojc/350156
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Structural Activity of Unsaturated Alcohols and Oxidation Towards Pyrazinium Chlorochromate

Abstract: The kinetics of oxidation of allyl, crotonyl, styryl carbinol by pyrazinium chlorochromate (PzCC) has been investigated in 60% acetic acid medium.The order was found to be first order with respect to [oxidant], [substrate] and [H + .]. The rate of the oxidant decreased with increase in [PzCC] and increased with increase in the percentage of acetic acid. The addition of sodium perchlorate did not show any change in rate constant. Based on the kinetic results, the mechanism between unsaturated alcohol and chro… Show more

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“…To eliminate phenylic acid from wastewater and lessen its damaging impact on the environment, a variety of techniques have been explored. The numerous treatment techniques include electrochemical processes, biodegradation, biosorption, pervaporation, membrane separation processes 8 , extraction, ion exchange methods 9,10 , distillation, adsorption [11][12][13] and oxidation procedures [14][15][16][17] .…”
Section: Introductionmentioning
confidence: 99%
“…To eliminate phenylic acid from wastewater and lessen its damaging impact on the environment, a variety of techniques have been explored. The numerous treatment techniques include electrochemical processes, biodegradation, biosorption, pervaporation, membrane separation processes 8 , extraction, ion exchange methods 9,10 , distillation, adsorption [11][12][13] and oxidation procedures [14][15][16][17] .…”
Section: Introductionmentioning
confidence: 99%