Structural and corrosion protection properties of electrochemically deposited nano-sized Zn–Ni alloy coatings

Electrodeposition of nanocrystalline Zn–Ni coatings with single gamma phase from an alkaline bath

“…There are three zinc-DMH complexes and three nickel-DMH complexes in the electrolyte, respectively, i.e., 3 ] − . This is due to the fact that the formation constants (log 10 (β)) of zinc-DMH complexes and nickel-DMH complexes are 2.48, 5.82, 8.18 and 3.05, 4.94, 6.18, respectively [31] and the bath pH is 9-10.…”

“…This is obtained by alloying zinc with Fe group metals such as Fe, Co and Ni. In recent years, the interest in Zn-Ni alloys has been increasing as a substitute for cadmium coatings [3,4] due to its eco-friendly properties [5,6]. In addition, Zn-Ni alloy coatings have attracted considerable attention in the aerospace and energy generation owing to its excellent corrosion resistance at high temperature and severe oxidizing conditions [7].…”

Corrosion mechanism of nanocrystalline Zn–Ni alloys obtained from a new DMH-based bath as a replacement for Zn and Cd coatings

“…3. According to the literature[39], the height of the peaks gives prediction about 254 the quantity of related phase in deposits. Zn-Ni alloys are 231 γ-Ni 5 Zn 21 phase which is the typical phase observed in Zn-13% ~ 15% Ni.…”

Corrosion characteristics of ZnNiCo ternary alloy electrochemically deposited by using different anodes

“…Prema Tozaru i dr. [23] gustine struja korozije dvojnih legura Zn-Ni deponovanih iz sulfatnih kupatila kreću se u intervalu od 7,7 do 44,8 µA cm ) predstavio je i Mosavat i ostali (Mosavat et al). [24] Rezultati Eliaza i dr. (Eliaz et al), [8] pokazuju da vrijednosti gustine struje korozije za dvojne prevlake Zn-Ni deponovane iz hloridnih kupatila iznose 14,9-39,5 µA cm …”

“…Tozar i dr. (Tozar et al), [23] pokazali su da se vrijednosti impedance kreće za R 1 = 0,586-1,465 kΩ. Slične rezultate su pokazali i drugi autori [27].…”