“…Note that magnetic structures obtained by our study are realized in the realistic ratio J H /U = 0. 25 [42][43][44] . This compound has Cu 2 O 3 combined two-leg-ladder structure, and is insulator.…”
We investigated the iron-based ladder compounds (Ba,Cs)Fe2Se3. Their parent compounds, BaFe2Se3 and CsFe2Se3, have different space groups, formal valences of Fe and magnetic structures. Electrical resistivity, specific heat, magnetic susceptibility, X-ray diffraction and powder neutron diffraction measurements were conducted to obtain temperature and composition phase diagram of this system. Block magnetism observed in BaFe2Se3 is drastically suppressed with Cs doping. In contrast, stripe magnetism observed in CsFe2Se3 is not so fragile against Ba doping. New type of magnetic structure appears in intermediate compositions, which is similar to stripe magnetism of CsFe2Se3, but inter-ladder spin configuration is different. Intermediate compounds show insulating behavior, nevertheless finite T -linear contribution in specific heat was obtained at low temperatures.
“…Note that magnetic structures obtained by our study are realized in the realistic ratio J H /U = 0. 25 [42][43][44] . This compound has Cu 2 O 3 combined two-leg-ladder structure, and is insulator.…”
We investigated the iron-based ladder compounds (Ba,Cs)Fe2Se3. Their parent compounds, BaFe2Se3 and CsFe2Se3, have different space groups, formal valences of Fe and magnetic structures. Electrical resistivity, specific heat, magnetic susceptibility, X-ray diffraction and powder neutron diffraction measurements were conducted to obtain temperature and composition phase diagram of this system. Block magnetism observed in BaFe2Se3 is drastically suppressed with Cs doping. In contrast, stripe magnetism observed in CsFe2Se3 is not so fragile against Ba doping. New type of magnetic structure appears in intermediate compositions, which is similar to stripe magnetism of CsFe2Se3, but inter-ladder spin configuration is different. Intermediate compounds show insulating behavior, nevertheless finite T -linear contribution in specific heat was obtained at low temperatures.
“…Chemical pressure by Ca substitution for Sr as well as physical pressure reduces the interlayer distances 19 and increases the twisting of the CuO 2 chain. 20 As a consequence, about 30-50 % of the O(c) atoms reduce their distance to the nearest Cu(l) atom to a value comparable with the typical Cu-O apex distance for HTSC's. 20 A transfer of holes from the chains to the ladder sites concurrent with Ca substitution was predicted theoretically 21 and was also inferred from various experiments.…”
Section: Introductionmentioning
confidence: 99%
“…20 As a consequence, about 30-50 % of the O(c) atoms reduce their distance to the nearest Cu(l) atom to a value comparable with the typical Cu-O apex distance for HTSC's. 20 A transfer of holes from the chains to the ladder sites concurrent with Ca substitution was predicted theoretically 21 and was also inferred from various experiments. 11,12,22 Despite all this wealth of information on the ladder compounds, however, there remains a considerable amount of controversy, and a more direct determination of the sitespecific hole distribution is still missing.…”
“…(e) The resonance at 12 cm −1 is characterized by an enhanced effective mass, typical for collective excitations like the CDW. (f) We do not observe any resonance for x = 9 when the system looses its one-dimensionality [23,24]. 21].…”
mentioning
confidence: 99%
“…A number of magnetic, electronic and structural properties display an anomaly around 170 K [4,24,[28][29][30] which may indicate some type of phase transition. We suggest that this transition is due to a second CDW which develops in the chain sub-system of Sr 14 Cu 24 O 41 .…”
The electrodynamic response of the spin-ladder compound Sr14−xCaxCu24O41 (x = 0, 3, 9) has been studied from radiofrequencies up to the infrared. At temperatures below 250 K a pronounced absorption peak appears around 12 cm −1 in Sr14Cu24O41 for the radiation polarized along the chains/ladders (E c). In addition a strongly temperature dependent dielectric relaxation is observed in the kHz -MHz range. We explain this behavior by a charge density wave which develops in the ladders sub-system and produces a mode pinned at 12 cm −1 . With increasing Ca doping the mode shifts up in frequency and eventually disappears for x = 9 because the dimensionality of the system crosses over from one to two dimensions, giving way to the superconducting ground state under pressure.
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