Structural and Hysteretic Properties of La0.7Ca0.3−xSrxMnO3 Manganites Using the Hydrothermal Route

Investigation of the impact of A-site cation disorder on the structure, magnetic properties, and magnetic entropy change of trisubstituted divalent ions in La0.7(Ba,Ca,Sr)0.3MnO3 manganite

“…49 The spin–orbit splitting of the La 3d level (∼16.8 eV) was identical for all the compounds and was close to those observed for perovskite samples. 48–51…”

“…48 The complex structure of La 3d can be explained by innerlevel electron transfer from the ligand orbitals to metal 3d orbitals. 49 The spin-orbit splitting of the La 3d level (B16.8 eV) was identical for all the compounds and was close to those observed for perovskite samples. [48][49][50][51] The Ba 3d core levels exhibit doublet structures, as shown in Fig.…”

“…49 The spin-orbit splitting of the La 3d level (B16.8 eV) was identical for all the compounds and was close to those observed for perovskite samples. [48][49][50][51] The Ba 3d core levels exhibit doublet structures, as shown in Fig. 8c.…”

“…48 Initially, similar O 1s spectra were observed for other perovskite manganites, with various interpretations and contradictions, referring to oxygen bonding with the various elements of the compound, defects and vacancies. [48][49][50][51][53][54][55][58][59][60][61] Based on several studies, the deconvolution of the O 1s spectra obtained for LBCS compounds segregates the contribution from the three different types of oxygen species as shown in Fig. 10.…”