Structural and magnetic properties of RE2O2SO4 (RE = Gd, Tb, Dy and Ho) oxides featuring large direct and inverse magnetocaloric effect

Chen, Wang; Wang, Jinyi; Yang, Fuyu; Zhang, Yikun; Li, Lingwei

doi:10.1016/j.ceramint.2024.06.388

Ceramics International

2024

DOI: 10.1016/j.ceramint.2024.06.388

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Structural and magnetic properties of RE2O2SO4 (RE = Gd, Tb, Dy and Ho) oxides featuring large direct and inverse magnetocaloric effect

Wang Chen,

Jinyi Wang,

Fuyu Yang

et al.

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Cited by 3 publications

References 41 publications

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Structural, magnetic, and magnetocaloric characterizations of geometrically-frustrated SrRE2O4 (RE = Gd, Dy, Ho, Er) oxides for low-temperature cooling applications

Lin,

Wu,

Sun

et al. 2024

Ceramics International

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Structural, magnetic, and magnetocaloric characterizations of geometrically-frustrated SrRE2O4 (RE = Gd, Dy, Ho, Er) oxides for low-temperature cooling applications

Lin,

Wu,

Sun

et al. 2024

Ceramics International

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Effects of Cr3+ incorporation on structure, surface morphology, and the magnetocaloric effect in La0.8Sr0.2Mn1-Cr O3 ceramics by means of first-principles calculations and wet chemical method

Xie,

Zheng,

et al. 2024

Ceramics International

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Magnetic phase transition and cryogenic magnetocaloric properties in the RE6Ni2.3In0.7 (RE = Ho, Er, and Tm) compounds

Xie,

Wang,

Yang

et al. 2024

Journal of Applied Physics

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The magnetocaloric (MC) properties in many rare-earth (RE)-containing magnetic solids have been intensively investigated, which are aimed to develop suitable candidates for cryogenic magnetic cooling applications and to better understand their intrinsic magnetic characters. We herein fabricated the RE-rich RE6Ni2.3In0.7 (RE = Ho, Er, and Tm) compounds and investigated their structural, magnetic, and MC properties by experimental determination and theoretical calculations. All of these RE6Ni2.3In0.7 compounds crystallize in an Ho6Co2Ga-type structure with an orthogonal Immm space group and order magnetically around the temperatures of 10.6 and 33.0 K for Ho6Ni2.3In0.7, 11.0 K for Er6Ni2.3In0.7, and 7.6 K for Tm6Ni2.3In0.7, respectively. Large cryogenic reversible MC effects were observed in these RE6Ni2.3In0.7 compounds. Moreover, their MC parameters of maximum magnetic entropy changes, relative cooling powers, and temperature-averaged magnetic entropy change are comparable with those of some recently updated cryogenic MC materials.

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Structural and magnetic properties of RE2O2SO4 (RE = Gd, Tb, Dy and Ho) oxides featuring large direct and inverse magnetocaloric effect

Cited by 3 publications

References 41 publications

Structural, magnetic, and magnetocaloric characterizations of geometrically-frustrated SrRE2O4 (RE = Gd, Dy, Ho, Er) oxides for low-temperature cooling applications

Structural, magnetic, and magnetocaloric characterizations of geometrically-frustrated SrRE2O4 (RE = Gd, Dy, Ho, Er) oxides for low-temperature cooling applications

Effects of Cr3+ incorporation on structure, surface morphology, and the magnetocaloric effect in La0.8Sr0.2Mn1-Cr O3 ceramics by means of first-principles calculations and wet chemical method

Magnetic phase transition and cryogenic magnetocaloric properties in the RE6Ni2.3In0.7 (RE = Ho, Er, and Tm) compounds

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