Structural and magnetic properties of Fe and Ni co-doped SnO₂ nanoparticles prepared by co-precipitation method

Abstract

In this research work Fe and Ni co-doped Tin oxide (SnO2) nanoparticles have been prepared by co-precipitation method. The samples were prepared at various combination of Fe and Ni from 0% up to 10%. The produced nanoparticles were studied by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), UV-Vis Spectrophotometer, Fourier Transformation Infrared Spectroscopy (FTIR) and Vibrating Sample Magnetometer (VSM). The XRD study reveals the formation of rutile structure of the undoped and doped SnO2 nanoparticles with the average crystallite size of 1.5-10.8 nm. Metal oxide bonding is confirmed through FTIR measurement. Optical band gap redshift (3.9 to 3.64 eV) with doping of Fe and Ni atom is observed. SEM image confirms the formation of spheroidal nanoparticles and size of the nanoparticle varies from 36 to 15 nm. The VSM study shows the ferromagnetic phase transition at 7% Ni, Fe doped SnO2 nanoparticles. This ferromagnetism arises for the oxygen vacancies and defect states. Further, increase of doping concentration of 10%, nanoparticles show the phase transition from ferromagnetic to paramagnetic. Such transition can be applicable in hyperthermia treatment and memory devices.

Synthesis and Characterization of High Dielectric Constant Zirconia Nano-Rods for Advanced Sensors and Energy Storage Applications

“…This approach is advantageous due to its simplicity, low cost, environmental friendliness, and ability to produce high-purity ceramic oxides with controlled morphology and crystallinity. [24][25][26][27][28][29] This study is expected to contribute significantly to the fundamental understanding of ZrO 2 and may open new avenues for its applications…”