Structural and magnetic properties of dinuclear Cu(II) complexes featuring triazolyl-naphthalimide ligands

Abstract

Naphthalimide based ligands have received significant attention for their ability to act as secondary building units (SBUs) for metal-containing network structures. The potentially bridging 1,2,4-triazole containing N- (1,2,4-triazolyl

Synthesis and characterisation of Fe(III) and Co(III) complexes of thiazole-containing thiosemicarbazone ligands

“…Thiosemicarbazone-based ligands are ideal for such a purpose as they are readily and reliably constructed from simple precursors allowing introduction of a large range of substituents. [23][24][25][26][27][28][29][30][31][32] Here we report the synthesis and characterization of three thiazole containing thiosemicarbazone ligands (L1-L3, Fig. 1) and their complexation with Fe(III) and Co(III).…”

Synthesis, Characterization, and Biological Profiling of Ruthenium(II)-Based 4-Nitro- and 4-Amino-1,8-naphthalimide Conjugates

“…− counterion (centroid•••F2 = 3.322 Å). Interestingly, unlike other naphthalimide-containing complex structures, 65,66 no immediately obvious structure extension influences (e.g., π−π stacking between neighboring complexes, formation of πstacked layers, etc.) are arising from the naphthalimide moiety.…”

A supramolecular Tröger's base derived coordination zinc polymer for fluorescent sensing of phenolic-nitroaromatic explosives in water

“…1a,5a,b,7a,13b,16 In contrast to the conventional CPs, the miniaturized coordination polymers can have entirely different size-dependent physico-chemical properties. 17 Scaling down the particle size of bulk crystalline CPs to their micro-/nanoscale regime is expected to facilitate their easy dispersion in aqueous media and increases the interaction with analytes and thus enhances the sensing ability.…”

“…One such material that has received immense interest, in recent years, for NACs detection is luminescent metal–organic frameworks (MOFs) or coordination polymers (CPs) on account of their easy synthesis, unique and functional properties, permanent porosity, high thermal/chemical stability, systematically tuneable electronic structures, intriguing structural diversity, good recyclability, and so on. 1a , 5a , b , 7a , 13b , 16 In contrast to the conventional CPs, the miniaturized coordination polymers can have entirely different size-dependent physico-chemical properties. 17 Scaling down the particle size of bulk crystalline CPs to their micro-/nanoscale regime is expected to facilitate their easy dispersion in aqueous media and increases the interaction with analytes and thus enhances the sensing ability.…”