In these studies we report the catalytic proficiency of two Eu and Pr doped CeO 2 nanoparticles on the thermal behaviour of powder AP and CSPs samples. A co-precipitation method was used for synthesizing Eu and Pr doped CeO 2 nanoparticles and they were characterized by XRD, FTIR, and SEM with EDX. The catalytic proficiency of both Eu and Pr doped CeO 2 nanoparticles were investigated by utilizing TG-DSC technique. The FWO, KAS, and Starink methods were used to determine activation energies of all catalyzed AP and CSPs samples. The catalytic proficiency increased by addition of Eu and Pr doped CeO 2 nanoparticles and decomposition temperature decreased in the presence of catalyst. The activation energy decreased by the addition of Eu and Pr doped CeO 2 nanoparticles in AP and CSPs, the burning rate of CSPs found to increase by the addition of Eu and Pr doped CeO 2 nanoparticles. The Pr doped CeO 2 nanoparticles showed good catalytic efficiency on AP and CSPs that reduced the decomposition temperature around 70 °C for AP and 20 °C for CSPs. The activation energy of CSPs catalyzed by Pr doped CeO 2 nanoparticles reported 150.12, 147.60, and 146.83 kJ mol −1 by FWO, KAS, and Starink method respectively which decreases in existence of catalyst in CSPs.