Structural and optical properties of europium‐ and titanium‐doped Y₂O₃ nanoparticles

Abstract

Luminescent nanoparticles of Y 2 O 3 doped with europium (Eu) and/or titanium (Ti) were synthesized using modified sol-gel routes. The crystalline cubic phase was confirmed using X-ray powder diffraction (XRD). Particle morphology and size were evaluated using scanning and transmission electron microscopy. High-resolution transmission electron microscopy showed that the synthesis method affected the average particle size and the Fourier transform of the images showed the lattice plane distances, indicating that the samples presented high crystallinity degree in accordance with the XRD pattern. The Ti valence was investigated using X-ray absorption near edge spectroscopy and the tetravalent form was the dominant oxidizing state in the samples, mainly in Eu and Ti co-doped Y 2 O 3 . Optical behaviour was investigated through X-ray excited optical luminescence and photoluminescence under ultraviolet-visible (UV-vis) and vacuum ultraviolet (VUV) excitation. Results indicated that Eu 3+ is the emitting centre in samples doped with only Eu and with both Eu and Ti with the 5 D 0 ! 7 F 2 transition as the most intense, indicating Eu 3+ in a noncentrosymmetric site. Finally, in the Eu,Ti-doped Y 2 O 3 system, Ti 3+ (or Ti IV ) excitation was observed but no Ti emission was present, indicating a very efficient energy transfer process from Ti to Eu 3+ . These results can aid the development of efficient nanomaterials, activated using UV, VUV, or X-rays. K E Y W O R D Scoconut water, energy transfer, luminescence, proteic sol-gel, synchrotron radiation, Y 2 O 3

Current Developments in Emerging Lanthanide‐Doped Persistent Luminescent Scintillators and Their Applications

“…[68] Chen et al [69] investigated the relationship between the Xray excited PersL of Sr 2 MgSi 2 O 7 : Eu 2 + , Dy 3 + and the temperature, reaction pH, Eu/Dy ratio, and calcination time through this method, providing an optimization strategy for the practical application of phosphors. Teixeira et al [70] reported Eu 3 + , Ti 3 + / Ti 4 + co-doped Y 2 O 3 nanoparticles by coconut water-based solgel method and the obtained nanomaterials with particle size of 30~100 nm. Strong and PersL of Eu 3 + can be realized by effective energy transfer from Ti 3 + /Ti 4 + to Eu 3 + .…”