Structural and some Mechanical Properties of Parquetina Nigrescens Pod Nanoparticles Reinforced Mixed Matrix Membrane for Dental Applications

Abstract

Polylactic acid (PLA) is a biocompatible, and biodegradable thermoplastic. It is renewable being produced by bacterial fermentation of potatoes, sugarcane, or corn starch. PLA has been attempted in many applications to replace petroleum-based polymers because some of its mechanical properties are excellent and it can be processed easily but low toughness and thermal stability are setbacks from one application to another. To improve on mechanical properties of the PLA to be suitable as biomaterials for dental and other applications, this study focuses on synthesis of Parquetinanigrescens pod nanoparticles (PNPNP) as reinforcements in the PLA to engineer new nanocomposites for biomedical applications. Chemical, structural and some mechanical properties were investigated. TEM result indicates an average size of 14.14 nm of the PNPNP used for reinforcing the PLA. Fourier Transform Infrared Spectrograph establishes a reduction in the amount of light transmitted by the PLA. This is due to PNPNP additions with changes in the wavenumbers of the observed peaks affirming formation of new compounds due to interactions of the PLA molecules and PNPNP. X-ray diffractograms reaffirms new compound formations. Moreover, there are enhancements in mechanical properties up to 3% by weight of PNPNP addition to the PLA with about 92% improvement in the impact toughness.