Structural Aspect of Platinum Coordination Compounds: Part II. Monomeric Pt11 Compounds with PtA3B and PtA2B2 Composition

Main Group Metal Chemistry

2020

Structural data of cis-Pt(η2-P2L)(XL)2 (X = Ge or Te), cis-Pt(η2-P2L)(η2-X2L) (X = As, Ge or Te) and trans-Pt(η2-P,TeL)2 were classified and analyzed. The chelating ligands create varieties of metallocyclic rings, which open in the sequence: 83.1° (GeGeGe) < 83.8° (AsC2As) < 86.2° (PC2P) < 88.5° (PC2Te) < 89.7° (PC3P) ~ 89.7° (GeGe2Ge). The structural data are compared and discussed with the complexes of an inner coordination spheres Pt(η2-P2L)(XL)2 (X = O, N, CN, B, Cl, S, Se, Si, Br or I), Pt(η2-P2L)(η2- X2L) (X = O, N, S, Se or Si), and Pt(η2-P,SiL)2.

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Section: Discussionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Organodiphosphines in PtP₂X₂ (X = As, Ge or Te) derivatives – Structural aspects

Main Group Metal Chemistry

2020

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“…There are numerous published structural studies of platinum complexes. In our previous reviews (Holloway and Melnik, 2002, 2003, 2004a, 2004b, 2005 classified and analyzed almost 2000 platinum complexes.…”

Section: Introductionmentioning

confidence: 99%

“…The former can be divided into coordination, hydrate, ionization, linkage and polymerization sub-categories, and the latter can be divided into geometric (cis-trans, fac-mer), optical, ligand and distortion isomerism. The huge area of platinum coordination chemistry has been surveyed (Holloway and Melnik, 2002, 2003, 2004a, 2004b, 2005 with over 200 isomeric examples noted. In this review we analyzed and classified structural data for Pt(0)P 3 , Pt(0)P 4 and Pt(II)P 4 derivatives.…”

Section: Introductionmentioning

confidence: 99%

Structures of Pt(0)P₃, Pt(0)P₄ and Pt(II)P₄ – Distortion isomers

Main Group Metal Chemistry

2020

In this review are analyzed and classified crystallographic and structural parameters of P(0)P3, Pt(0) P4 and Pt(II)P4 derivatives – distortion isomers. Some of the isomers are differing not only by degree of distortion but also by crystal class. There are three types of organo-phosphines which build up the respective geometry about the platinum atoms. In Pt(0)P3 a distorted trigonal planar geometry is build up by three monodentate PPh3 ligands. In Pt(0)P4 a tetrahedral geometry with various degree of distortion is build up by a pair of homo-bidentate ligands. In Pt(II)P4 isomers a square-planar geometries with various degree of distortion are build up by bidentate-P,P’donor ligands, (except one example of isomers, where a tetradentate is involved). The bidentate-P,P’-donor ligands form: four-(PNP,PCP), five-(PC2P) and six-(PC3P) metallocyclic rings. The tetradentate forms five-(PC2P). There are some cooperative effects between Pt–P bond distances and the metallocyclic rings, and at the same time a distortion of the respective geometry increases.

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Organophosphines in PtPCOX (X = N, Cl, S), PtPCNX (X = Cl, S, Br, I, As) and PtPCClX (X = S, I, As) derivatives: structural aspects

2018

Transit Met Chem