2008
DOI: 10.1016/j.jssc.2008.01.026
|View full text |Cite
|
Sign up to set email alerts
|

Structural aspects of fast copper mobility in Cu6PS5Cl—The best solid electrolyte from series

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1

Citation Types

0
10
0

Year Published

2008
2008
2022
2022

Publication Types

Select...
7
1

Relationship

0
8

Authors

Journals

citations
Cited by 18 publications
(10 citation statements)
references
References 17 publications
0
10
0
Order By: Relevance
“…Apart from the temperature induced disorder (asso ciated with thermal lattice vibrations) and structural (static and dynamic) disorder, which are characteris tic of pure Cu 6 PS 5 I(Cl) crystals, the crystals of Cu 6 PS 5 I 1 ⎯ x Cl x solid solutions undergo a composi tional disorder. According to [17], the effect of the influence of different types of disorder on the Urbach energy in crystals of solid solutions is described by the relationship (5) where the (E U ) X and (E U ) C are the contributions from the structural and compositional disorders of the crys tals to the Urbach energy, respectively; and (E U ) T is the contribution from the temperature dependent types of disorder to the Urbach energy. A comparison of (4) and (5) has demonstrated that (E U ) X, C ≡ (E U ) 0 and (E U ) T ≡ (E U ) 1 /(exp(θ E /T) -1).…”
Section: Optical Absorption and The Processes Of Disordering Of The Cmentioning
confidence: 99%
See 2 more Smart Citations
“…Apart from the temperature induced disorder (asso ciated with thermal lattice vibrations) and structural (static and dynamic) disorder, which are characteris tic of pure Cu 6 PS 5 I(Cl) crystals, the crystals of Cu 6 PS 5 I 1 ⎯ x Cl x solid solutions undergo a composi tional disorder. According to [17], the effect of the influence of different types of disorder on the Urbach energy in crystals of solid solutions is described by the relationship (5) where the (E U ) X and (E U ) C are the contributions from the structural and compositional disorders of the crys tals to the Urbach energy, respectively; and (E U ) T is the contribution from the temperature dependent types of disorder to the Urbach energy. A comparison of (4) and (5) has demonstrated that (E U ) X, C ≡ (E U ) 0 and (E U ) T ≡ (E U ) 1 /(exp(θ E /T) -1).…”
Section: Optical Absorption and The Processes Of Disordering Of The Cmentioning
confidence: 99%
“…F43c F43c by the change in the symmetry Cc [5]. It has been found that, in the phase transition tempera ture region, the Cu 6 PS 5 I(Cl) crystals exhibit an anom alous behavior of the electrical, thermodynamic, acoustic, and optical properties [2,3,[6][7][8][9].…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…At T = T II , with lowering temperature, the symmetry change → occurs, whereas, at T = T I the symmetry change → Cс takes place [3]. In the Cu 6 PS 5 Cl crystal, at T I = (160 ± 1) K, only the superi onic phase transition takes place, which is also the fer roelastic transition and is accompanied by the symme try change → Cс [4].…”
Section: Introductionmentioning
confidence: 98%
“…[33][34][35] Cu 6 PS 5 Cl has been of particular interest due to its high performance and copper mobility. 36,37 This material has shown better conductivities than other materials in the same family. In a similar case to the enargite materials, synthesis of the argyrodites is done in sealed ampule or vacuum based methods.…”
mentioning
confidence: 99%