Among the family of rare earth (RE) dopants, the doping of first member Ce into GaN is the least studied system. This article reports structure properties of Ce-doped GaN realized by technique of ion implantation. Ce ions were implanted into metal organic chemical vapor deposition grown n-and p-GaN/sapphire thin films at doses 3 Â 10 14 and 2 Â 10 15 cm À2 . X-ray diffraction scans and Raman scattering measurements exhibited expansion of lattice in the implanted portion of the samples. First order Raman scattering spectra show appearance of several disorder-activated Raman scattering modes in addition to typical GaN features. A dose-dependent decrease in intensity of E 2 mode was observed in Raman the spectra of the implanted samples. Ultraviolet Raman spectra of implanted samples show complete quenching of photoluminescence emission and appearance of multiple A 1 (LO) phonon scattering modes up to fifth order. Moreover, a decrease in intensity and an increase in line width of LO modes as a function of wavenumber were observed for implanted samples.