Structural Classes with a Sole Bearing Contact of Chained Structural Units

Banaru, D. A.; Aksenov, S. M.; Banaru, A. M.; Potekhin, K. A.

doi:10.1134/s1063774523600333

Crystallogr. Rep.

2023

DOI: 10.1134/s1063774523600333

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Structural Classes with a Sole Bearing Contact of Chained Structural Units

D. A. Banaru,

S. M. Aksenov,

A. M. Banaru

et al.

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2024

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Cited by 2 publications

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A contribution to the crystal chemistry and topology of organic thiosulfates: bis(1-methylpiperazinium)·S₂O₃·H₂O versus 1-methylpiperazinediium·S₂O₃·3H₂O

Charkin,

Banaru,

Ivanov

et al. 2024

Acta Crystallogr B Struct Sci Cryst Eng Mater

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Single crystals of two new compounds, (C5H14N2)S2O3·H2O (1) and (C5H13N2)2S2O3·3H2O (2), were isolated from the reaction products of 1-methylpiperazine, sulfuric acid, and barium thiosulfate in aqueous media. The crystal structures have been determined by single-crystal X-ray diffraction. In agreement to the previous observations, the organic template may contribute to the formation of thiosulfates both as mono- and diprotonated species, but this is the first case where both products are reported for the same organic compound. In both structures 1 and 2, complex nets of hydrogen bonds involve all cations, anions and water molecules. Comparisons are made to the structures of other thiosulfates containing mono- or diprotonated diamine species.

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A contribution to the crystal chemistry and topology of organic thiosulfates: bis(1-methylpiperazinium)·S₂O₃·H₂O versus 1-methylpiperazinediium·S₂O₃·3H₂O

Charkin,

Banaru,

Ivanov

et al. 2024

Acta Crystallogr B Struct Sci Cryst Eng Mater

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On the Subset of Intermolecular Contacts Generating a Molecular Crystal: Topological Features of Organic Minerals

2022

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Structural Classes with a Sole Bearing Contact of Chained Structural Units

Cited by 2 publications

References 53 publications

A contribution to the crystal chemistry and topology of organic thiosulfates: bis(1-methylpiperazinium)·S₂O₃·H₂O versus 1-methylpiperazinediium·S₂O₃·3H₂O

A contribution to the crystal chemistry and topology of organic thiosulfates: bis(1-methylpiperazinium)·S₂O₃·H₂O versus 1-methylpiperazinediium·S₂O₃·3H₂O

On the Subset of Intermolecular Contacts Generating a Molecular Crystal: Topological Features of Organic Minerals

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Structural Classes with a Sole Bearing Contact of Chained Structural Units

Cited by 2 publications

References 53 publications

A contribution to the crystal chemistry and topology of organic thiosulfates: bis(1-methylpiperazinium)·S2O3·H2O versus 1-methylpiperazinediium·S2O3·3H2O

A contribution to the crystal chemistry and topology of organic thiosulfates: bis(1-methylpiperazinium)·S2O3·H2O versus 1-methylpiperazinediium·S2O3·3H2O

On the Subset of Intermolecular Contacts Generating a Molecular Crystal: Topological Features of Organic Minerals

Contact Info

Product

Resources

About

A contribution to the crystal chemistry and topology of organic thiosulfates: bis(1-methylpiperazinium)·S₂O₃·H₂O versus 1-methylpiperazinediium·S₂O₃·3H₂O

A contribution to the crystal chemistry and topology of organic thiosulfates: bis(1-methylpiperazinium)·S₂O₃·H₂O versus 1-methylpiperazinediium·S₂O₃·3H₂O