Structural, dielectric, optical and ferroelectric property of urea succinic acid crystals grown in aqueous solution containing maleic acid

Singh, Bholey; Sinha, Nidhi; Singh, Neelam; Kumar, Krishan; Gupta, Manoj; Kumar, Binay

doi:10.1016/j.jpcs.2010.09.010

Cited by 36 publications

(4 citation statements)

References 14 publications

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“…The title compound crystal (point group 2) belongs to one of these point groups. The obtained d 33 value for the grown crystal is 29.8 pC/N, which is higher than some other piezoelectric crystals [33][34][35] as presented in Table 3.…”

Section: Resultsmentioning

confidence: 60%

Structure, crystalline perfection, mechanical, second harmonic generation efficiency, laser damage threshold and piezoelectric properties of bis nicotinamidium bis D-tartrate 1.25-hydrate single crystals

Murugan¹,

Ramasamy²

2015

Optical Materials

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Section: Resultsmentioning

confidence: 60%

Structure, crystalline perfection, mechanical, second harmonic generation efficiency, laser damage threshold and piezoelectric properties of bis nicotinamidium bis D-tartrate 1.25-hydrate single crystals

Murugan¹,

Ramasamy²

2015

Optical Materials

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“…The peaks observed at 3185 cm −1 , 2812 cm −1 and 496 cm −1 respectively belongs to the NH stretching of primary amine, aromatic C─H stretching vibration and out-of-plane ring deformations [20]. The peak at 3477 cm −1 corresponds to OH vibrations, while at 1027 cm −1 belongs to stretching vibrations of C─N [21]. The sharp intense peaks at 3555 cm −1 , 1526 cm −1 , 1287 cm −1 and 741 cm −1 correspond to N─H stretching, NO 2 asymmetric stretching, CH stretching and NH 2 rocking vibration respectively [22,23].…”

Section: Single Crystal X-ray Diffraction Analysismentioning

confidence: 96%

Third order nonlinearity examined by pulsed and CW lasers: an organic urea barbituric acid (UBA) single crystal for optical limiting application with DFT study

Suresh,

Jauhar,

Girisun

et al. 2024

Mater. Res. Express

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Bulk size of urea barbituric acid single crystal which have not been reported earlier was successfully grown by slow evaporation solution growth method. Single-crystal XRD brought out the lattice constant and the crystal system is observed to be monoclinic with space group P. Functional group of UBA were determined by FT-IR. Title crystal is entirely visible from 270 to 900 nm with linear optical energy gap value to be 4.50 eV. The observed HOMO-LUMO energy gap was 5.21 eV. Thermally, UBA crystal is found to be stable up to 184˚C. The Cp value of UBA increases from 1.21 to 1.58 J/gK with the temperature difference from 30 to 100˚C. UBA shows good photoconductive nature and it found to be positive and Laser Damage Threshold (LDT) value of UBA crystal is 0.97 GW/cm2. Hardness testing confirms that UBA crystal belongs to soft nature category. Dielectric properties of UBA crystal are studied as a function of frequency and temperature. Third order NLO properties of the UBA crystal were studied under CW and pulsed lasers (ns) regimes using Z-scan technique. Good Optical limiting (OL) response confirms the efficiency of UBA crystal to be used as optical limiters for protection towards short pulse lasers.

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“…As mentioned above, the LTA crystal belongs to noncentrosymmetric crystal system (space group P2 1 ), which is required for the piezoelectric property. The determined d 33 value for LTA crystal is 47 pC/N, which is higher than glycine phosphate (1.03 pC/N) [14], urea succinic acid (5.00 pC/N) [15], triglycine sulfate (conventional) (10.22 pC/N) [16] and glycine picrate (18 pC/N) [17].…”

Section: Piezoelectric Studymentioning

confidence: 99%

Investigation on crystalline perfection, mechanical, piezoelectric and ferroelectric properties of L-tartaric acid single crystal

Murugan¹,

Ramasamy²

2014

AIP Conference Proceedings

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A study on crystalline perfection, optical, dielectric, mechanical, laser damage threshold and NLO properties of glycine added potassium dihydrogen phosphate single crystals AIP Conf.Abstract. Polar organic nonlinear optical material, L-tartaric acid single crystals have been grown from slow evaporation solution growth technique. Single crystal X-ray diffraction study indicates that the grown crystal crystallized in monoclinic system with space group P2 1 . Crystalline perfection of the crystal has been evaluated by high resolution X-ray diffraction technique and it reveals that the crystal quality is good and free from structural grain boundaries. Mechanical stability of the crystal has been analyzed by Vickers microhardness measurement and it exhibits reverse indentation size effect. Piezoelectric d 33 co-efficient for the crystal has been examined and its value is 47 pC/N. The ferroelectric behaviour of the crystal was analyzed by polarization-electric field hysteresis loop measurement.

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Structural, dielectric, optical and ferroelectric property of urea succinic acid crystals grown in aqueous solution containing maleic acid

Cited by 36 publications

References 14 publications

Structure, crystalline perfection, mechanical, second harmonic generation efficiency, laser damage threshold and piezoelectric properties of bis nicotinamidium bis D-tartrate 1.25-hydrate single crystals

Structure, crystalline perfection, mechanical, second harmonic generation efficiency, laser damage threshold and piezoelectric properties of bis nicotinamidium bis D-tartrate 1.25-hydrate single crystals

Third order nonlinearity examined by pulsed and CW lasers: an organic urea barbituric acid (UBA) single crystal for optical limiting application with DFT study

Investigation on crystalline perfection, mechanical, piezoelectric and ferroelectric properties of L-tartaric acid single crystal

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