Structural diversity, computational outputs, and supramolecular solid-state assemblies in sustaining the coordination chemistry of zinc, cadmium, and mercury dithiocarbamates

Shotonwa, Ibukun O.; Osifeko, Olawale L.; Amos, Samuel F.; Akande, Emmanuel O.; Adejare, Adeniyi A.; Olaoye, Toluwalase R.; Akinwande, Blessing B.; Adeoluwa, Zainab A.; Benjamin, Ngozi F.; Lambo, Michael O.; Obietikponah, Chizzy F.; Chukwuyem, David N.; Ifagbuyi, Peter O.; Opeseyi, Abiodun A.; Ibrahim, Omeiza O.; Oladele, Zainab A.; Adeyemi, Ayobami E.; Oresanya, Zechariah O.; Ogunkoya, Oluwatobi I.; Onwudiwe, Damian

doi:10.1016/j.molstruc.2024.138242

Journal of Molecular Structure

2024

DOI: 10.1016/j.molstruc.2024.138242

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Structural diversity, computational outputs, and supramolecular solid-state assemblies in sustaining the coordination chemistry of zinc, cadmium, and mercury dithiocarbamates

Ibukun O. Shotonwa,

Olawale L. Osifeko,

Samuel F. Amos

et al.

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Asynchronous Synergetic Remediation Strategy for Cd-Contaminated Soil via Passivation and Phytoremediation Technology

Cao,

Lv,

Zhang

et al. 2024

Agronomy

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Cadmium (Cd) contamination in soil has emerged as a significant challenge for agricultural production. Phytoremediation and passivation are key techniques for remediating Cd-contaminated soil. However, few studies have focused on the synergistic effects of these two techniques. In this work, the effectiveness of synergetic remediation strategies, both synchronous and asynchronous, utilizing passivation and phytoremediation techniques, was explored. The results of pot experiments and field experiments indicated that optimal remediation effects were obtained by asynchronous synergetic remediation, removing over 80% of bioavailable Cd within 14 days. Mechanistic studies conducted using XPS analysis, soil property analysis, and microbial diversity analysis confirmed that the chelation effect of SDD and soil pH value are the primary factors contributing to the effectiveness of both remediation strategies. In contrast, the variations in microbial populations are identified as the crucial factors influencing the varying outcomes of the two sequential remediation approaches. This research demonstrates that asynchronous synergistic remediation is a promising strategy for mitigating Cd contamination in soil.

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Asynchronous Synergetic Remediation Strategy for Cd-Contaminated Soil via Passivation and Phytoremediation Technology

Cao,

Lv,

Zhang

et al. 2024

Agronomy

View full text Add to dashboard Cite

show abstract

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Structural diversity, computational outputs, and supramolecular solid-state assemblies in sustaining the coordination chemistry of zinc, cadmium, and mercury dithiocarbamates

Cited by 1 publication

References 227 publications

Asynchronous Synergetic Remediation Strategy for Cd-Contaminated Soil via Passivation and Phytoremediation Technology

Asynchronous Synergetic Remediation Strategy for Cd-Contaminated Soil via Passivation and Phytoremediation Technology

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