2024
DOI: 10.1002/zaac.202400169
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Structural Diversity of Cadmium Complexes with N‐Heterocyclic Carbene‐Isothiocyanate Zwitterionic Ligand

Jyoti Sharma,
Suman Das,
Archana Jain
et al.

Abstract: In this study, we discuss the synthesis and structural characterization of three N‐heterocyclic carbene isothiocyanate zwitterionic ligands, 1,3‐bis(2,6‐diisopropylphenyl)‐2‐N‐phenyl‐thiocarbamoyl imidazolium (ImDipp ‐CSNPh, L1), 1,3‐bis(tert‐butyl)‐2‐N‐phenylthiocarbamoyl imidazolium (ImtBu‐CSNPh, L2) and 1,3‐bis(2,4,6‐trimethylphenyl)‐2‐N‐phenylthiocarbamoyl imidazolium (ImMes‐CSNPh, L3) and their cadmium complexes,  [(ImDipp‐CSNPh)2CdCl][CdCl3] (1) and [(ImtBu‐CSNPh)2Cd2Cl6] (2). Both bench‐stable cadmium c… Show more

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