2024
DOI: 10.1021/acs.macromol.4c00018
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Structural Effect of Cyclic Olefin Cross-Linkers on Long-Wave Infrared-Transmitting Sulfur Polymers

Miyeon Lee,
Se Gyu Jang,
Hyeonuk Yeo
et al.

Abstract: The structural characteristics of the organic crosslinker greatly affect the potential infrared (IR) optics applications of sulfur polymers synthesized through the inverse vulcanization reaction. Unlike elemental sulfur, organic cross-linkers induce various absorptions in the IR region and leave organic moieties that affect the IR transmittance, even after inverse vulcanization. Most of the cyclic olefin cross-linkers [e.g., dicyclopentadiene (DCPD)] investigated so far are expected to produce side reactions a… Show more

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