Structural effects of the carboxylate anion on Ru-catalyzed C—H arylation of (hetero)aromatic substrates containing N-donor directing group

Gnatiuk, I. G.; Nikolaeva, K. A.; Shepelenko, K. E.; Chernyshev, V. M.

doi:10.1007/s11172-024-4158-1

Russ Chem Bull

2024

DOI: 10.1007/s11172-024-4158-1

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Structural effects of the carboxylate anion on Ru-catalyzed C—H arylation of (hetero)aromatic substrates containing N-donor directing group

I. G. Gnatiuk,

K. A. Nikolaeva,

K. E. Shepelenko

et al.

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2024

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Cited by 3 publications

References 38 publications

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Regioselective arylation of (het)aryl fragment in 2-(het)aryl-1-methylperimidines under ruthenium catalysis

Shepelenko,

Gnatiuk,

Aleksandrov

et al. 2024

Mendeleev Communications

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Regioselective arylation of (het)aryl fragment in 2-(het)aryl-1-methylperimidines under ruthenium catalysis

Shepelenko,

Gnatiuk,

Aleksandrov

et al. 2024

Mendeleev Communications

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Simple Access to 3-(Hetero)arylated Derivatives of 2-Furoic Acid via Ru(II)-Catalyzed C3-H Arylation of 2-Furoylimidazole

Chernyshev,

Ananikov,

Shepelenko

et al. 2024

Synthesis

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A new approach for the preparation of a variety of 3-arylated 2-furoic acid derivatives has been developed. The approach involves selective Ru-catalyzed C3-H arylation of the furan moiety of readily available 2-furoyl-1-methylimidazole (using imidazole as a removable N-donor directing group), subsequent N-methylation, and nucleophilic substitution of the imidazole moiety with N, O, S, and C nucleophiles.

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Selective Ru-Catalyzed C3–H Alkenylation of Furan-2- and Thiophene-2-carboxylic Acids with Internal Alkynes

Shepelenko,

Gnatiuk,

Chernyshev

2024

Russ J Gen Chem

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Structural effects of the carboxylate anion on Ru-catalyzed C—H arylation of (hetero)aromatic substrates containing N-donor directing group

Cited by 3 publications

References 38 publications

Regioselective arylation of (het)aryl fragment in 2-(het)aryl-1-methylperimidines under ruthenium catalysis

Regioselective arylation of (het)aryl fragment in 2-(het)aryl-1-methylperimidines under ruthenium catalysis

Simple Access to 3-(Hetero)arylated Derivatives of 2-Furoic Acid via Ru(II)-Catalyzed C3-H Arylation of 2-Furoylimidazole

Selective Ru-Catalyzed C3–H Alkenylation of Furan-2- and Thiophene-2-carboxylic Acids with Internal Alkynes

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