“…Intense Raman mode formed at 220 cm -1 (BFO), 219 cm -1 (BFCO0.5), 209 cm -1 (BFCO1) and 196 cm -1 (BFCO2) is related to Fe-O vibration in FeO4 tetrahedron. Similarly, other phonon modes observed for BFO (285 cm -1 , 317 cm -1 and 424 cm -1 ), BFCO0.5 (284 cm -1 , 318 cm -1 and 426 cm -1 ), BFCO1 (279 cm -1 , 320 cm -1 and 427 cm -1 ), BFCO1.5 (275 cm -1 , 321 cm -1 and 427 cm -1 ) and BFCO2 (274 cm -1 , 324 cm -1 and 428 cm -1 ) owes to vibration of Fe-O in the FeO6 octahedron [29]. It is also important to notice an emergence of additional peak for compositions x ≥ 0.01 at 558 cm -1 (BFCO1), 561 cm -1 (BFCO1.5) and 564 cm -1 (BFCO2) as shown in fig.…”