Equiatomic
and chemically ordered FeRh and MnRh compounds feature
a first-order metamagnetic phase transition between antiferromagnetic
and ferromagnetic order in the vicinity of room temperature, exhibiting
interconnected structural, magnetic, and electronic order parameters.
We show that these two alloys can be combined to form hybrid metamagnets
in the form of sputter-deposited superlattices and alloys on single-crystalline
MgO substrates. Despite being structurally different, the magnetic
behavior of the alloys with substantial Mn content resembles that
of the FeRh/MnRh superlattices in the ultrathin individual layer limit.
For FeRh/MnRh superlattices, dissimilar lattice distortions of the
constituent FeRh and MnRh layers at the antiferromagnetic–ferromagnetic
transition cause double-step transitions during cooling, while the
magnetization during the heating branch shows a smooth, continuous
trend. For Fe50‑x
Mn
x
Rh50 alloy films, the substitution of
Mn at the Fe sites introduces an effective tensile in-plane strain
and magnetic frustration in the highly ordered epitaxial films, largely
influencing the phase transition temperature T
M (by more than 150 K). In addition, Mn acts as a surfactant,
enabling the growth of continuous thin films at higher temperatures.
Thus, the introduction of hybrid FeRh–MnRh systems with adjustable
parameters provides a pathway for the realization of tunable spintronic
devices based on magnetic phase transitions.