Structural Features Guiding the Design of Liquid-Crystalline Elastomeric Fluorescent Force Sensors

Abstract

Liquid single crystal elastomers (LSCEs) containing carbazole fluorogenic components alter their luminescence when they are stretched along the director direction. The differential luminescent behavior arises from the distinct interaction between the carbazole fluorophores and their local environment before and after the application of the mechanical input. Indeed, the uniaxial deformation of the material, along its anisotropic direction, forces a closer mesogen–fluorophore interaction, which leads to the quenching of the carbazole luminescence. Importantly, this intermolecular interaction is intimately related to the intrinsic order present in the LSCE. As a result, the amount of light emitted by the material in the form of fluorescence diminishes upon deformation. Thus, the application of mechanical stimuli to liquid-crystalline elastomers furnishes to two interconvertible states for the system with distinct optical properties (with either different emission color or fluorescence intensity). The initial state of the material is completely restored once the applied force is removed. In this way, this kind of macromolecular system can transduce mechanical events into detectable and processable optical signals, thus, having great potential as optical force sensors. In this context, the realization of the distinct structural factors that govern the interactions established between the mesogenic and fluorogenic units at the supramolecular level upon deformation is essential for the development of efficient LSCE-based force sensors. In fact, not only the density of carbazole units and their connection to the main polymer backbone, but also the presence of long range molecular order in the system and the type of mesophase exhibited by the LSCE are key factors for the conception of efficient force sensors based on these self-organized polymer networks. In this review, we present a comprehensive and systematic description of the different features that control the mechanoluminescent behavior of fluorescent liquid-crystalline elastomers and will guide the future design of LSCE-based force sensors with improved performances.

Programming Positive Mechanofluorescence in Liquid Crystalline Elastomers

“…In previous studies, we have shed light on the structural factors that govern the intermolecular interactions established between the mesogenic and the fluorogenic units, which, in turn, determine the mechanofluorescent response observed macroscopically. , Specifically, we have explored how the anchoring mode (side-on vs end-on) of the carbazole fluorophores to the elastomeric network influences the sensing abilities of the final material . Similarly, we have studied the luminescent response when applying mechanical forces as a function of the length of the flexible alkyl chain connecting the fluorophore to the main polymer backbone .…”