Structural insight into the multifunctionality of non-stoichiometric BNT ferroelectrics

Shi, Jing; Wang, Jicong; Zhu, Fangyuan; Tian, Wenchao; Hua, Weibo; Fan, Huiqing; Yang, Jing; Liu, Laijun; Liu, Xiao

doi:10.1039/d4ta05841k

J. Mater. Chem. A

2024

DOI: 10.1039/d4ta05841k

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Structural insight into the multifunctionality of non-stoichiometric BNT ferroelectrics

Jing Shi,

Jicong Wang,

Fangyuan Zhu

et al.

Abstract: Fascinatingly high saturation polarization and electric-field induced strain make bismuth sodium titanium (BNT) promising alternatives. Interestingly, significantly improved oxide-ion conductive capacity and ultrahigh asymmetric strain can be stimulated respectively, both...

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High‐Sulfur‐Loading Gel Cathode Employing a Self‐Supporting Composite Matrix for Lithium‐Polysulfide Batteries

Li,

Yuan,

et al. 2024

Energy Tech

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Aimed at the application drawbacks of lithium‐polysulfide semiflow battery involved with low utilization of active material and inevitable shuttle effect, a self‐supporting porous substrate characterized by high porosity and outstanding conductivity is developed in this study, which consists of cotton‐derived nanofiber and graphene wrapped on the nanofiber. Then a gelable polymer poly‐(vinylidenefluoride‐hexafluoropropylene) is further integrated into the porous substrate for fabricating novel PS gel cathode. The as‐prepared composite matrix possesses strong PS adsorption/loading ability by gelation as well as favorable electron/ion transport pathway, which not only provides effective restriction toward PS migration and shuttle, but also actualizes rapid redox conversion of the localized active species. Consequently, the resultant PS gel cathode demonstrates high reversible capacity, and excellent cycle and rate capability even at a high sulfur loading up to 9.0 mg cm−2.

show abstract

High‐Sulfur‐Loading Gel Cathode Employing a Self‐Supporting Composite Matrix for Lithium‐Polysulfide Batteries

Li,

Yuan,

et al. 2024

Energy Tech

View full text Add to dashboard Cite

show abstract

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Structural insight into the multifunctionality of non-stoichiometric BNT ferroelectrics

Abstract: Fascinatingly high saturation polarization and electric-field induced strain make bismuth sodium titanium (BNT) promising alternatives. Interestingly, significantly improved oxide-ion conductive capacity and ultrahigh asymmetric strain can be stimulated respectively, both...

Cited by 1 publication

References 65 publications

High‐Sulfur‐Loading Gel Cathode Employing a Self‐Supporting Composite Matrix for Lithium‐Polysulfide Batteries

High‐Sulfur‐Loading Gel Cathode Employing a Self‐Supporting Composite Matrix for Lithium‐Polysulfide Batteries

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